State-resolved translation energy distributions for NCO photodissociation

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State-resolved translation energy distributions for NCO photodissociation

The photodissociation dynamics of NCO have been examined using fast beam photofragment translational spectroscopy. Excitation of the 10 , 30 , and 10 30 2 transitions of the B̃ 2P←X̃ P band produces N(S)1CO photofragments exclusively, while excitation of the 10 30 3 transition yields primarily N(D)1CO photoproducts. The translational energy @P(ET)# distributions yield D0~N–CO!52.3460.03 eV, and D...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2001

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.1369132